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You can buy "Iron Man: Rise of Technovore" on Apple TV, Rakuten TV, Blockbuster, SF Anytime as download or rent it on Blockbuster, Apple TV, Rakuten TV, SF Anytime online.
Iron Man enlists the help of ruthless vigilante the Punisher to track down War Machine's murderer. All the while, he's being pursued by S.H.I.E.L.D. agents Black Widow and Hawkeye, who suspect his involvement in a recent terrorist plot.