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You can buy "Captain America: The First Avenger" on Apple TV, Google Play Movies as download or rent it on Google Play Movies, Apple TV online.
During World War II, Steve Rogers is a sickly man from Brooklyn who's transformed into super-soldier Captain America to aid in the war effort. Rogers must stop the Red Skull – Adolf Hitler's ruthless head of weaponry, and the leader of an organization that intends to use a mysterious device of untold powers for world domination.