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You can buy "Iron Man: Rise of Technovore" on Apple TV, Google Play Movies, Rakuten TV as download or rent it on Google Play Movies, Apple TV, Rakuten TV online.
Iron Man enlists the help of ruthless vigilante the Punisher to track down War Machine's murderer. All the while, he's being pursued by S.H.I.E.L.D. agents Black Widow and Hawkeye, who suspect his involvement in a recent terrorist plot.