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You can buy "Superman: Brainiac Attacks" on Apple TV, Google Play Movies as download or rent it on Apple TV, Google Play Movies online.
Embittered by Superman's heroic successes and soaring popularity, Lex Luthor forms a dangerous alliance with the powerful computer/villain Brainiac. Using advanced weaponry and a special strain of Kryptonite harvested from the far reaches of outer space, Luthor specifically redesigns Brainiac to defeat the Man of Steel.