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You can buy "Metallica/Slayer/Megadeth/Anthrax: The Big 4 - Live from Sofia, Bulgaria" on Apple TV as download or rent it on Apple TV online.
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When the 'Big Four,' Metallica, Slayer, Megadeth and Anthrax shared a stage together on June 22nd, 2010, in Sofia, Bulgaria, it was the moment their fans had waited decades for. That monumental show was beamed live into over 1000 theaters worldwide via satellite.