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Currently you are able to watch "Brad Pitt & Jennifer Aniston: Hollywood's Couple of the Year" streaming on Freevee for free with ads or buy it as download on Amazon Video. It is also possible to rent "Brad Pitt & Jennifer Aniston: Hollywood's Couple of the Year" on Amazon Video online
This documentary explores the sequence of events that led A-listers Brad Pitt and Jennifer Aniston to one another, and recounts their relationship in the international spotlight.