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You can buy "Pokémon: The Rise of Darkrai" on Apple TV, Amazon Video as download or rent it on Apple TV, Amazon Video online.
Ash and friends (this time accompanied by newcomer Dawn) arrive at an idyllic village on their way to their next Pokemon contest, where chaos will soon erupt with the prophecy of two Pokemon Gods (Dialga and Palkia) and the arrival of a mysterious, seemingly deadly Pokemon named Darkrai, which has the power to distort space and time.